To date iodine transfer polymerization itp organoheteroatom mediated polymerization omrp 28 37 cobalt mediated polymerization comrp and reversible addition fragmentation chain transfer raft polymerization have been proven efficient in the radical polymerization of vinyl esters. Acetate in the radical polymerization the free radi cal polymerization of vinyl acetate in solution strongly depends on the solvent 3 8 according to density func tion theory or dft 8 we have considered the electroneg ativity of co sn and zn transition metals as simple estimates for the reactivity of co acac 2 zncl 2 and sncl 2 catalysts. You can see that this will lead us back where we started as we now have a new free radical when this unpaired electron comes to roost on that carbon atom.
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